Variable temperature (-115 to -155 degrees C) studies of the infrared spectra (3200-400 cm(-1)) of 4-fluoro-1-butene, CH2=CHCH2CH2F, dissolved in liquid krypton have been carried out. The infrared spectra of the gas and solid as well as the Raman spectra of the gas, liquid, and solid have also been recorded from 3200 to 100 cm(-1). From these data, an enthalpy difference of 72 +/- 5 cm(-1) (0.86 +/- 0.06 kJ.mol(-1)) has been determined between the most stable skew-gauche II conformer (the first designation refers to the position of the CH2F group relative to the double bond, and the second designation refers to the relative positions of the fluorine atom to the C-C(=C) bond) and the second most stable skew-traps form. The third most stable conformer is the skew-gauche I with an enthalpy difference of 100 +/- 7 cm(-1) (1.20 +/- 0.08 kJ.mol(-1)) to the most stable form. Larger enthalpy values of 251 +/- 12 cm(-1) (3.00 +/- 0.14 kJ.mol(-1)) and 268 +/- 17 cm(-1) (3.21 +/- 0.20 kJ.mol(-1)) were obtained for the cis-traps and cis-gauche conformers, respectively. From these data and the relative statistical weights of one for the cis-traps conformer and two for all other forms, the following conformer percentages are calculated at 298 K: 36.4 +/- 0.9% skew-gauche II, 25.7 +/- 0.1% skew-traps, 22.5 +/-0.2% skew-gauche I, 10.0 +/- 0.6% cis-gauche, and 5.4 +/- 0.2% cis-trans. The potential surface describing the conformational interchange has been analyzed and the corresponding two-dimensional Fourier coefficients were obtained. Nearly complete vibrational assignments for the three most stable conformers are proposed and some fundamentals for the cis-traps and the cis-gauche conformers have been identified. The structural parameters, dipole moments, conformational stability, vibrational frequencies, infrared, and Raman intensities have been predicted from ab initio calculations and compared to the experimental values when applicable. The adjusted r(0) structural parameters have been determined by combining the ab initio predicted parameters with previously reported rotational constants from the microwave data. These experimental and theoretical results are compared to the corresponding quantities of some similar molecules.