Fluid Phase Equilibria, Vol.134, No.1-2, 151-161, 1997
Isobaric Vapor-Liquid-Equilibrium of Binary-Mixtures of 1-Propanol Plus Chlorobenzene and 2-Propanol Plus Chlorobenzene
Isobaric vapor-liquid equilibria were obtained for the system 1-propanol + chlorobenzene at 20 and 100 kPa and for the system 2-propanol + chlorobenzene at 100 kPa using a dynamic still. The experimental error in temperature was +/-0.1 K, in pressure +/-0.01 kPa and +/-0.1 kPa for the experiments carried out at 20 and 100 kPa, respectively, and in the liquid and vapor mole fraction 0.001. The two systems satisfy the point-to-point thermodynamic consistency test. Both systems show a positive deviation from ideality. The data were well correlated with the Margules, Van Laar, Wilson, NRTL and UNIQUAC equations.