Separation of esbiothrin and D-acetylene C permethrin in electric-mosquito coils by gas chromatography

Junyu Liu; Kyung Ho Row

Korean Journal of Chemical Engineering, Vol.27, No.1, 228-230, January, 2010

DOI10.1007/s11814-009-0288-2 Export Citation

Separation of esbiothrin and D-acetylene C permethrin in electric-mosquito coils by gas chromatography

Junyu Liu, and Kyung Ho Row^†

Department of Chemical Engineering, Inha University, 253 Yonghyun-dong, Nam-gu, Incheon 402-751, Korea

E-mail:

A simple and sensitive gas chromatography method for the simultaneous determination of esbiothrin and D-acetylene C permethrin in electric-mosquito coils using palmitic acid isopropyl as an internal standard was developed. The electric-mosquito coil samples were extracted with petroleum ether (60-90 ℃) and then centrifuged at 2,000 r/min for 2.0 min. The supernatant liquids were collected into a glass bottle and 2.0 μL of it was injected into the gas chromatograph. The results showed that the means recoveries of esbiothrin and acetylene c permethrin ranged from 100.2% to 99.8%. The relative standard deviation (n=10) of allylic permethrin and acetylene C permethrin was 0.44% and 0.26%, respectively. This method is a viable alternative tool to the existing gas chromatography methods for analyzing the content of allylic permethrin and D-acetylene C permethrin in electric-mosquito coil samples.

Keywords:Esbiothrin;Acetylene C Permethrin;Electric-mosquito Coils;Gas Chromatography

[References]

Ramesh A, Balasubramanian M, Analyst, 123, 1799 (1999)
Floore TG, Rathburn CB, Boike AH, Coughlin JS, Greer MJ, J. Am. Mosq. Control Assoc., 8, 58 (1992)
Narendra M, Bhatracharyulu NC, Padmavathi P, Varadacharyulu NC, Chemosphere, 67, 1065 (2007)
Matoba Y, Inoue A, Takimoto Y, J. Pesticide Sci., 29, 313 (2004)
Abdel-Mohdy FA, Fouda MG, Rehan MF, Aly AS, Carbohydr. Polym., 73, 92 (2008)
Mosha FW, Njau RJ, Alfred J, Med. Veter. Entomolo., 6, 44 (1992)
Ramesh A, Vijayalakshmi A, J. Environ. Monitoring, 3, 191 (2001)
Lentza-Rizos CH, Avramides EJ, Visi E, J. Chromatogr. A, 921, 297 (2001)
Ling YC, Huang IP, J. Chromatogr. A, 695, 75 (1995)
Du Z, Zhu X, Xiang R, Chem. Res. Appl., 9, 429 (1997)
Wu Q, Liu K, Chin. J. Ana. Chem., 21, 1095 (1993)
Wu Q, Liu K, Ana. Lab., 12, 7 (1993)
Sakulku U, Nuchuchua O, Uawongyart N, Puttipipatkhachorn S, Soottitantawat A, Ruktanonchai U, Int. J. Phytorem., 105-111, 372 (2009)

[Related Articles]

[1] Ramesh A, Balasubramanian M, Analyst, 123, 1799 (1999)

[2] Floore TG, Rathburn CB, Boike AH, Coughlin JS, Greer MJ, J. Am. Mosq. Control Assoc., 8, 58 (1992)

[3] Narendra M, Bhatracharyulu NC, Padmavathi P, Varadacharyulu NC, Chemosphere, 67, 1065 (2007)

[4] Matoba Y, Inoue A, Takimoto Y, J. Pesticide Sci., 29, 313 (2004)

[5] Abdel-Mohdy FA, Fouda MG, Rehan MF, Aly AS, Carbohydr. Polym., 73, 92 (2008)

[6] Mosha FW, Njau RJ, Alfred J, Med. Veter. Entomolo., 6, 44 (1992)

[7] Ramesh A, Vijayalakshmi A, J. Environ. Monitoring, 3, 191 (2001)

[8] Lentza-Rizos CH, Avramides EJ, Visi E, J. Chromatogr. A, 921, 297 (2001)

[9] Ling YC, Huang IP, J. Chromatogr. A, 695, 75 (1995)

[10] Du Z, Zhu X, Xiang R, Chem. Res. Appl., 9, 429 (1997)

[11] Wu Q, Liu K, Chin. J. Ana. Chem., 21, 1095 (1993)

[12] Wu Q, Liu K, Ana. Lab., 12, 7 (1993)

[13] Sakulku U, Nuchuchua O, Uawongyart N, Puttipipatkhachorn S, Soottitantawat A, Ruktanonchai U, Int. J. Phytorem., 105-111, 372 (2009)