Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex

Munro-Leighton C; Feng Y; Zhang J; Alsop NM; Gunnoe TB; Boyle PD; Petersen JL

Inorganic Chemistry, Vol.47, No.14, 6124-6126, 2008

Munro-Leighton C, Feng Y, Zhang J, Alsop NM, Gunnoe TB, Boyle PD, Petersen JL

Synthesis and isolation of the monomeric octahedral platinum(IV) amido complex (NCN)PtMe2NHPh have been accomplished upon deprotonation of the amine complex [(NCN)PtMe2(NH2Ph)][OTf]. The preliminary reactivity of the amido ligand has been explored.