화학공학소재연구정보센터
Inorganic Chemistry, Vol.47, No.20, 9140-9142, 2008
GaCl3-Assisted Cyclization Reactions in Hypersilyl(trimethylsilyl)aminodichlorophosphine
Hypersilyl(trimethylsilyl)aminodichlorophosphine, (hyp)N(SiMe3)PCl2, was treated with GaCl3, which resulted in the formation of an interesting novel bicycle, composed of a four-membered SiNP2 ring and a five-membered P2Ga2Cl ring. In the presence of Me3SiN3, the same reaction provided access to a cyclo-2-phospha-4-sila-1,3-diazenium tetrachlorogallate. The tree chloro-cyclo-phosphasiladiazane was obtained by the addition of nucleophilic bases.