Site Preferences of NH4+ in Its Solid Solutions with Cs2WS4 and Rb2WS4 from Multinuclear Solid-State MAS NMR

Jakobsen HJ; Bildsoe H; Skibsted J; Hansen MR; Brorson M; Srinivasan BR; Bensch W

Inorganic Chemistry, Vol.48, No.5, 1787-1787, 2009

Jakobsen HJ, Bildsoe H, Skibsted J, Hansen MR, Brorson M, Srinivasan BR, Bensch W

Solid solutions of NH4+ in Cs2WS4 and Rb2WS4 are obtained by precipitation/crystallization from aqueous solutions. By means of N-14, Rb-11, and Cs-133 magic angle spinning NMR, compositions and extraordinarily accurate NH4+-site preferences are established for these materials.