Adsorption of methane on porous metal carboxylates

Ji Sun Lee; Sung Hwa Jhung; Ji Woong Yoon; Young Kyu Hwang; Jong-San Chang

Journal of Industrial and Engineering Chemistry, Vol.15, No.5, 674-676, September, 2009

DOI10.1016/j.jiec.2009.09.043 Export Citation

Adsorption of methane on porous metal carboxylates

Ji Sun Lee, Sung Hwa Jhung^{1, †}, Ji Woong Yoon, Young Kyu Hwang, and Jong-San Chang^†

Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology, P.O. Box 107, Yusung, Daejeon 305-600, Republic of Korea
¹Department of Chemistry, Kyungpook National University, Daegu 702-701, Republic of Korea

E-mail:,

Porousmetal carboxylates such as MIL-101 (Cr-terephthalate), MIL-100-Cr (Cr-trimesate) and MIL-100-Fe (Fe-trimesate) with very high porosity have been tested as potential adsorbents for methane storage materials. The MIL-101 shows one of the highest adsorption capacities for methane. The adsorption capacity per weight increases with increasing BET surface area or micropore volume irrespective of the structure, type of metal ions such as Cr^(3+) and Fe^(3+). This result suggests that the porous adsorbent for methane should have high porosity rather than special adsorption sites or structures.

Keywords:Adsorption;Methane;Metal carboxylate;Metal.organic framework

[References]

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Lozano-Castello D, Alcaniz-Monge J, de la Casa-Lillo MA, Cazorla-Amoros D, Linares-Solano A, Fuel, 81, 1777 (2003)
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Chung KH, Park BG, J. Ind. Eng. Chem., 15(3), 388 (2009)
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Ferey G, Chem. Soc. Rev., 37, 191 (2008)
Ferey G, Mellot-Draznieks C, Serre C, Millange F, Account Chem. Res., 38, 217 (2005)
Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J, Nature, 423, 705 (2003)
Kim JH, An JH, La YS, Jung JS, Jeong HM, Kim SM, Moon NG, Lee BW, Yoon YH, Il Choi Y, J. Ind. Eng. Chem., 14(2), 194 (2008)
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Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi OM, Science, 295, 469 (2002)
Duren T, Sarkisov L, Yaghi OM, Snurr RQ, Langmuir, 20(7), 2683 (2004)
Llewellyn PL, Bourrelly S, Serre C, Vimont A, Daturi M, Hamon L, De Weireld G, Chang JS, Hong DY, Hwang YK, Jhung SH, Ferey G, Langmuir, 24, 7245 (2008)
Morris RE, Wheatley PS, Angew. Chem. Intl. Ed., 47, 4966 (2008)
Ferey G, Serre C, Mellot-Draznieks C, Millange F, Surble S, Dutour J, Margiolaki I, Angew. Chem. Intl. Ed., 43, 6296 (2004)
Horcajada P, Surble S, Serre C, Hong DY, Seo YK, Chang JS, Greneche JM, Margiolaki I, Ferey G, Chem. Commun., 2820 (2007)
Jhung SH, Lee JH, Yoon JW, Serre C, Ferey G, Chang JS, Adv. Mater., 19(1), 121 (2007)
Ferey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Margiolaki I, Science, 309, 2040 (2005)
Rzepka M, Lamp P, de la Casa-Lillo MA, J. Phys. Chem. B, 102(52), 10894 (1998)
Jhung SH, Yoon JW, Lee JS, Chang JS, Chem. Eur. J., 13, 6502 (2007)
Jhung SH, Kim HK, Yoon JW, Chang JS, J. Phys. Chem. B, 110(19), 9371 (2006)
Jhung SH, Yoon JW, Kim HK, Chang JS, Bull. Korean Chem. Soc., 26, 1075 (2005)
Jhung SH, Lee JS, Yoon JW, Kim DP, Chang JS, Intl. J. Hydrogen Energy, 32, 4233 (2007)

[Referenced By]

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[1] Celzard A, Fierro V, Energy Fuels, 19(2), 573 (2005)

[2] Lozano-Castello D, Alcaniz-Monge J, de la Casa-Lillo MA, Cazorla-Amoros D, Linares-Solano A, Fuel, 81, 1777 (2003)

[3] Menon VC, Komarneni SJ, J. Porous Mater., 5, 43 (1998)

[4] ZareNezhad B, J. Ind. Eng. Chem., 15(2), 143 (2009)

[5] Chung KH, Park BG, J. Ind. Eng. Chem., 15(3), 388 (2009)

[6] Kitagawa S, Kitaura R, Noro SI, Angew. Chem. Intl. Ed., 43, 2334 (2004)

[7] Ferey G, Chem. Soc. Rev., 37, 191 (2008)

[8] Ferey G, Mellot-Draznieks C, Serre C, Millange F, Account Chem. Res., 38, 217 (2005)

[9] Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J, Nature, 423, 705 (2003)

[10] Kim JH, An JH, La YS, Jung JS, Jeong HM, Kim SM, Moon NG, Lee BW, Yoon YH, Il Choi Y, J. Ind. Eng. Chem., 14(2), 194 (2008)

[11] Seki K, Chem. Commun., 1496 (2001)

[12] Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi OM, Science, 295, 469 (2002)

[13] Duren T, Sarkisov L, Yaghi OM, Snurr RQ, Langmuir, 20(7), 2683 (2004)

[14] Llewellyn PL, Bourrelly S, Serre C, Vimont A, Daturi M, Hamon L, De Weireld G, Chang JS, Hong DY, Hwang YK, Jhung SH, Ferey G, Langmuir, 24, 7245 (2008)

[15] Morris RE, Wheatley PS, Angew. Chem. Intl. Ed., 47, 4966 (2008)

[16] Ferey G, Serre C, Mellot-Draznieks C, Millange F, Surble S, Dutour J, Margiolaki I, Angew. Chem. Intl. Ed., 43, 6296 (2004)

[17] Horcajada P, Surble S, Serre C, Hong DY, Seo YK, Chang JS, Greneche JM, Margiolaki I, Ferey G, Chem. Commun., 2820 (2007)

[18] Jhung SH, Lee JH, Yoon JW, Serre C, Ferey G, Chang JS, Adv. Mater., 19(1), 121 (2007)

[19] Ferey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Margiolaki I, Science, 309, 2040 (2005)

[20] Rzepka M, Lamp P, de la Casa-Lillo MA, J. Phys. Chem. B, 102(52), 10894 (1998)

[21] Jhung SH, Yoon JW, Lee JS, Chang JS, Chem. Eur. J., 13, 6502 (2007)

[22] Jhung SH, Kim HK, Yoon JW, Chang JS, J. Phys. Chem. B, 110(19), 9371 (2006)

[23] Jhung SH, Yoon JW, Kim HK, Chang JS, Bull. Korean Chem. Soc., 26, 1075 (2005)

[24] Jhung SH, Lee JS, Yoon JW, Kim DP, Chang JS, Intl. J. Hydrogen Energy, 32, 4233 (2007)