Applied Surface Science, Vol.254, No.16, 5247-5251, 2008
Effect of heat-pretreatment of the graphite rod on the quality of SWCNTs by arc discharge
Single-walled carbon nanotubes (SWCNTs) have been synthesized in high yield by the dc arc discharge technique under heat-pretreatment of the graphite rod conditions. Before executing arc discharge, the graphite rods containing the catalysts were heat treated at 600, 700, 800 and 900 degrees C for 1-3 h, respectively. Effects of heat-pretreatment of the graphite rod on the quality of SWCNTs by arc discharge were investigated. The heat-treatment temperature and time were found to be crucial for a high yield of high-purity SWCNTs. Optimum parameter was found to be at the heat-treatment temperature of 800 degrees C for 2 h. The SWCNTs synthesized under the optimum condition have better field-emission characteristics. The turn-on field needed to produce a current density of 10 mu A/cm(2) is found to be 1.9 V/mu m and the threshold field where current density reaches 10 mA/cm(2) is 3.9 V/mu m. (C) 2008 Elsevier B.V. All rights reserved.
Keywords:single-walled carbon nanotubes;arc discharge;heat-pretreatment;Raman spectroscopy;field emission