Applied Surface Science, Vol.255, No.7, 3983-3988, 2009
Structure and gas-barrier properties of amorphous hydrogenated carbon films deposited on inner walls of cylindrical polyethylene terephthalate by plasma-enhanced chemical vapor deposition
The influence of radio-frequency (RF) power on the structure and gas permeation through amorphous hydrogenated carbon films deposited on cylindrical polyethylene terephthalate (PET) samples is investigated. The results show that a higher radio-frequency power leads to a smaller sp(3)/sp(2) value but produces fewer defects with smaller size. The permeability of PET samples decreases significantly after a.C:H deposition and the RF only exerts a small influence. However, the coating uniformity, color, and wettability of the surface are affected by the RF power. A higher RF power results in to better uniformity and it may be attributed to the combination of the high-density plasma and sample heating. (C) 2008 Elsevier B. V. All rights reserved.
Keywords:Amorphous hydrogenated carbon film;Plasma-enhanced chemical vapor deposition;Radio frequency;Raman spectroscopy;Uniformity