This paper investigated the gaseous formaldehyde degradation by the amine-functionalized SiO2/TiO2 photocatalytic films for improving indoor air quality. The films were synthesized via the cocondensation reaction of methyltrimethoxysilane ( MTMOS) and 3-aminopropyltrimethoxysilane (APTMS). The physicochemical properties of prepared photocatalysts were characterized with N-2 adsorption/desorption isotherms measurement, X-ray diffraction (XRD) and Fourier Transform Infrared spectroscopy (FT/IR). The effect of amine-functional groups and the ratio of MTMOS/APTMS precursors on the formaldehyde adsorption and photocatalytic degradation were investigated. The results showed that the formaldehyde adsorption and photocatalytic degradation of the APTMS-functionalized SiO2/TiO2 film was higher than that of SiO2/TiO2 film due to the surface adsorption on amine sites and the relatively high of the specific surface area of the APTMS-functionalized SiO2/TiO2 film (similar to 15 times higher than SiO2/TiO2). The enhancement of the formaldehyde degradation of the film can be attributed to the synergetic effect of adsorption and subsequent photocatalytic decomposition. The repeatability of photocatalytic film was also tested and the degradation efficiency was 91.0% of initial efficiency after seven cycles. (C) 2009 Elsevier B.V. All rights reserved.