Wetting phenomena of water droplets on solid are of crucial concern in our daily life as well as in engineering and science. The present paper describes the room temperature synthesis of super-hydrophobic silica films on glass substrates using trimethylethoxysilane (TMES) as a co-precursor. The coating sol was prepared by keeping the molar ratio of tetraethoxysilane (TEOS) precursor, methanol (MeOH) solvent, water (H2O) constant at 1:38.6:8.68, respectively, with 2 M NH4OH throughout the experiments and the TMES/TEOS molar ratio (M) was varied from 0 to 1.1. It was found that with an increase in M value, the hydrophobicity of the films increased, however the optical transmission decreased from 88% to 82% in the visible range. The hydrophobic silica films retained their hydrophobicity up to a temperature of 275 degrees C and above this temperature the films became superhydrophilic. The hydrophobic silica films were characterized by Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), Fourier Transform Infrared (FT-IR) spectroscopy, percentage of optical transmission, humidity test and static and dynamic contact angle measurements. (C) 2009 Published by Elsevier B. V.