화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.27, No.1, 152-158, January, 2010
DOI10.1007/s11814-009-0303-7  Export Citation
Adsorption of Nickel from aqueous solution by the use of low-cost adsorbents
Yasser Hannachi1, 2, †, Nicola Affanacivich Shapovalov1, and Aymen Hannachi2
  • 1Department of Colloid Chemistry, Belgorod State Technological University, 308012 Belgorod, Russia, Russian Federation
  • 2Department of Physic Chemistry, El Manar Preparatory Institute for Engineering Studies, 2092 El Manar II, Tunisia
E-mail:
The removal of Ni(II) from aqueous solution by different adsorbents was investigated. Calcined phosphate, red mud, and clarified sludge (a steel industry waste material) were used for the adsorption studies. The influence of pH, contact time, initial metal concentration, adsorbent nature and concentration on the selectivity and sensitivity of the removal process was investigated. The adsorption process was found to follow a first-order rate mechanism and rate constant was evaluated at 30 ℃. Langmuir and Freundlich adsorption isotherms fit well in the experimental data and their constants were evaluated. The thermodynamic equilibrium constant and the Gibbs free energy were calculated for each system. The adsorption capacity (q(max)) calculated from Langmuir isotherm and the values of Gibbs free energy obtained showed that calcined phosphate has a higher capacity and affinity for the removal of Ni(II) compared to the other adsorbents used in the study.
Keywords:Calcined Phosphate;Red Mud;Clarified Sludge;Langmuir Isotherm;Freundlich Isotherm;Gibbs Free Energy;First-order Rate Mechanism
  1. Bencko V, J. Hyg. Epidemiol. Microbiol. Immunol., 27, 237 (1983)
  2. Barton RT, Hogetveit AC, Cancer, 45, 3061 (1980)
  3. Norseth T, J. Toxicol. Environ. Health, 6, 1219 (1980)
  4. Morgan LG, Valerie U, Ann. Occup. Hyg., 38, 189 (1994)
  5. Kazimierz S, Kasprzak F, William S, Konstantin S, Mutat. Res., Fundam. Mol. Mech. Mutagen., 553, 67 (2003)
  6. Hanif MA, Nadeem R, Zafar MN, Akhtar K, Bhatti HN, J. Hazard. Mater., 145(3), 501 (2007)
  7. Babel S, Kurniawan TA, J. Hazard. Mater., 97(1-3), 219 (2003)
  8. Carrasco-Martin F, Mueden A, Centeno TA, Stoeckli F, Moreno-Castilla C, J. Chem. Soc. Faraday Trans., 93, 2211 (1997)
  9. van den Brandt P, Voorrips L, Hertz Picciotto I, Shuker L, Boeing H, Speijers G, Guittard C, Knowles M, Wolk A, Goldbohm A, Food Chem. Toxicol., 40, 387 (2002)
  10. Brach Papa C, Coulomb B, Boudenne JL, Cerda V, Theraulaz F, Anal. Chem. Acta, 457, 311 (2002)
  11. Patterson JW, Industrial wastewater treatment technology, second ed., Butterworth-Heinemann, London (1985)
  12. Tavlaride LL, Bae JH, Lee CK, Sep. Sci. Technol., 22, 581 (1987)
  13. Karabulut S, Karabakan A, Denizli A, Yurum Y, Sep. Purif. Technol., 18(3), 177 (2000)
  14. Brown PA, Gill SA, Allen SJ, Water Res., 34, 3907 (2000)
  15. Axtell NR, Sternberg SPK, Claussen K, Bioresour. Technol., 89(1), 41 (2003)
  16. Kandah MI, Sep. Purif. Technol., 35(1), 61 (2004)
  17. Poon CPC, Removal of Cd(II) from wastewater, in: Mislin H, Raverva O (Eds.), Cadmium in the Environment, Birkha User Basal, Switzerland, 6 (1986)
  18. Seco A, Gabaldon C, Marzal P, Aucejo A, J. Chem. Technol. Biotechnol., 74(9), 911 (1999)
  19. Corapcioglu MO, Haung CP, Water Res., 21, 1031 (1987)
  20. Reed BE, Nonavivakere SK, Sep. Sci. Technol., 27, 1985 (1992)
  21. Murano E, Ital. J. Biochem., 42, 303A (1993)
  22. Gao YM, Sengupta AK, Simpson D, Water Res., 29, 2195 (1995)
  23. Lothenbach B, Furrer G, Schulin R, Environ. Sci. Technol., 31, 1452 (1997)
  24. Gaikwad RW, Bhardwaj V, Indian J. Environ. Health, 37, 111 (1975)
  25. Srivastava RK, Ayachi AK, Sehgal V, Ind. J. Environ. Prot., 21, 154 (2000)
  26. Reddad Z, Gerente C, Andres Y, Cloirec P, Environ. Sci. Technol., 36, 2067 (2002)
  27. Celis R, Hermosin JC, Environ. Sci. Technol., 34, 4593 (2000)
  28. Cooper C, Jiang JQ, Ouki S, J. Chem. Technol. Biotechnol., 77(5), 546 (2002)
  29. Muzzarelli RAA, Rocchetti R, Metal adsorption by modified chitins, in: Thomson R (Ed.), Trace Metal Removal from Aqueous Solution, The Royal Society of Chemistry, London, 44 (1986)
  30. Kadirvelu K, Namasivayam C, Adv. Environ. Res., 7, 471 (2003)
  31. Sag Y, Kutsal T, Biochem. Eng. J., 6, 145 (2000)
  32. Liu HL, Chen BY, Lan YW, Cheng YC, Chem. Eng. J., 97(2-3), 195 (2004)
  33. Scott J, Guang D, Naeramitmarnsuk K, Thabuot M, Amal R, J. Chem. Technol. Biotechnol., 77(1), 63 (2002)
  34. Panayotova M, Velikov B, J. Environ. Sci. Health Part A, 37, 139 (2002)
  35. Marshall WE, Johns MM, J. Chem. Technol. Biotechnol., 66(2), 192 (1996)
  36. Sun G, Shi WX, Ind. Eng. Chem. Res., 37(4), 1324 (1998)
  37. Lee TW, Khan ARM, Environ. Technol., 9, 1223 (1988)
  38. Lee DH, Moon H, Korean J. Chem. Eng., 18(2), 247 (2001)
  39. Ferro-Garcia MA, Rivera-Utrilla J, Rodriguez-Gordillo J, Bautista-Toledo I, Carbon, 26, 363 (1988)
  40. Zhou XD, Kot SC, J. Environ. Hyd., 3, 367 (1995)
  41. Namasivayam C, Periasamy K, Water Res., 27, 1663 (1993)
  42. Khan SA, Rehman R, Khan MA, Waste Manage., 15, 271 (1995)
  43. Sciban M, Klasnja M, Cent. Eur. J. Occup. Environ. Med., 9, 337 (2003)
  44. Sciban M, Klasnja M, Holz. Roh. Werkst., 62, 69 (2004)
  45. Gupta VK, Sharma S, Ind. Eng. Chem. Res., 42(25), 6619 (2003)
  46. Annadurai G, Juang RS, Lee DJ, Water Sci. Technol., 47, 185 (2003)
  47. Eslamzadeh T, Nasernejad B, Pour BB, Zamani A, Bygi ME, Iranian J. Sci. Technol. Trans. A, 28A1, 161 (2004)
  48. Standard Methods for Examination of Water and Wastewater, 20th ed., APHA, AWWA, Washington, DC, New York (1998)
  49. Namasivayam C, Yamuna RT, Chemosphere, 30, 561 (1995)
  50. Kandah MI, Sep. Purif. Technol., 35(1), 61 (2004)
  51. Kalyani S, Priya A, Rao SP, Krishnaiah A, Indian J. Environ. Health, 45, 163 (2003)
  52. Zouboulis AI, Lazaridis NK, Matis KA, J. Chem. Technol. Biotechnol., 77(8), 958 (2002)
  53. Dakiky M, Khamis M, Manassra M, Mer’eb M, Adv. Environ. Res., 6, 533 (2002)
  54. Weber TW, Chakraborti RK, AIChE J., 20, 228 (1974)
  55. McKay G, Blair HS, Gardener JR, J. Appl. Polym. Sci., 27, 3043 (1982)
  56. Calace N, Di Muro A, Nardi E, Petronio BM, Pietroletti M, Ind. Eng. Chem. Res., 41(22), 5491 (2002)