Three spent-decoked hydroprocessing catalysts and two corresponding fresh catalysts were tested as hot gas clean-up sorbents and compared with the zinc ferrite using a simulated coal gasification gas mixture. The catalysts deposited only by coke exhibited relatively good cleaning efficiency. The catalyst deposited by coke and metals such as vanadium and nickel was less efficient. The useful life of the spent hydroprocessing catalysts may be extended if utilized as hot gas clean-up sorbents.