Zonguldak bituminous coal, Tuncbilek and Soma-Merkez lignites were each separated into two sub-fractions, coal rich and mineral matter rich, using a centrifugal float-sink separation technique in heavy media. An isopropyl alcohol (IPA)-carbon tetrachloride (CCl4) mixture and a zinc chloride (ZnCl2) solution, with a specific gravity of 1.40 g cm(-3) at 25 degrees C were used as dense medium liquids. The addition of surface active agents (Triton X-100 and Brij-35) to the zinc chloride solution improved the removal of minerals. The recovery and purity of the final product (float) obtained from the heavy media separation depend on such parameters as the density of the medium, rotor speed and centrifugation time. The separation efficiency of each coal differed significantly. Particle size distributions of the coals and their float and sink fractions were analysed using a Laser Particle Size Analyser. A Scanning Electron Microscope (SEM) was used to interpret the liberation of minerals from the coal particles.