Anodic alumina materials exhibiting regular pore structure, microporosity, and extensive surface areas were prepared and characterized. The effects of current density, (J=12-35mA/cm2), anodization time (t=30-150min), and hydrothermal treatment on pore structure were investigated. Nitrogen sorption hysteresis was simulated using the corrugated pore structure model (CPSM). Pore size distributions, relative specific surface area (SCPSM/Sext=870-8645), microporosity (max33.0%), pore tortuosity (TCPSM=3.1-5.7), pore connectivity (c=3.02-4.85, Seaton's model), and nominal pore length values (i.e., Ns=3-10, from CPSM, and L=0.91-1.20, Seaton) were evaluated. Pore sizes dpore13nm deduced via CPSM simulation of gas sorption data were also detected by SEM imaging. A minimum external surface pore density of7.51010pores/cm2 was evaluated from the SEM micrograph. Anodization conditions and the following treatment caused a severe pore structure change. Pore tortuosity (TCPSM) changes inversely proportionally to pore connectivity (c), while the nominal pore length (Ns) varies proportionally to the number of pore length (L). It is concluded that materials possessing microporosity, regular pore architectures, and high surface areas can become potential candidate membranes for gas separation and catalytic reaction applications. They can also be used as templates in electrochemical applications (e.g., solar and fuel cells).