화학공학소재연구정보센터
Chemical Physics Letters, Vol.463, No.4-6, 345-348, 2008
On the role of molecular clustering on infrared absorption line shapes of acetylene in a supersonic expansion
A supersonic expansion containing acetylene seeded into Ar and produced from a circular nozzle is investigated using CW/cavity ring down spectroscopy, in the 1.5 mu m range. The results, also involving experiments with pure acetylene and acetylene-He expansions, as well as slit nozzles, demonstrate that the denser central section in the expansion is slightly heated by the formation of acetylene aggregates, resulting into a dip in the monomer absorption line profiles. Acetylene-Ar aggregates are also formed at the edge of the circular nozzle expansion cone. (C) 2008 Elsevier B. V. All rights reserved.