Chemical Physics Letters, Vol.474, No.1-3, 112-114, 2009
Observation of ultrafast internal conversion in fullerene anions in solution
The ultrafast decay rates of photoexcited C-60(-) and C-60(2-) ions have been measured in the condensed phase. The mechanism for decay is internal conversion, and the decay rate is a strong function of the charge on the ion. A bottleneck in the ground state recovery has also been detected, and its interpretation is discussed. (C) 2009 Elsevier B. V. All rights reserved.