Chemistry Letters, Vol.37, No.6, 586-587, 2008
Crystal structures and magnetic properties of [Mn-II(rac-pnH)(H2O)Cr-III(CN)(6)]center dot H2O and its dehydrated form
An irreversible single-crystal-to-single-crystal transformation is observed upon dehydration of [Mn-II(rac-pnH)(H2O)Cr-III(CN)(6)]center dot H2O. The virgin, dehydrated, and rehydrated phases are ferrimagnets with Curie temperature of 36, 70, and 36 K, respectively.