Chemistry Letters, Vol.38, No.1, 72-73, 2009
Three-dimensional Iron Glutarate with Five- and Six-coordinated Iron(II)-Oxygen Networks
A novel open framework iron(II)-carboxylate was synthesized and characterized. Four crystallographically different iron atoms have five- and six-coordinated geometry giving rise to 1D double metal-oxygen layers. The glutarate ligands link inorganic chains to give an interlocked 3D structure containing water. Magnetic measurement of iron-carboxylate compound shows canted antiferromagnetism around 4 K.