Chemistry Letters, Vol.38, No.8, 844-845, 2009
New Binaphthyl-based C-3-symmetric Chiral Hemilabile Monophosphite Ligands: Synthesis and Characterization of Their Platinum Complexes
In this paper, we report an easy and highly efficient methodology for the synthesis of novel binaphthyl-based chiral monophosphites with C-3-symmetry. The preparation of the respective platinum complexes and their characterization by suitable in situ NMR spectroscopic studies confirmed the noteworthy hemilabile potential of the new phosphite ligands.