화학공학소재연구정보센터
Chinese Journal of Chemical Engineering, Vol.17, No.4, 648-653, 2009
Model Study on a Submerged Catalysis/Membrane Filtration System for Phenol Hydroxylation Catalyzed by TS-1
This research is focused on the development of a simple design model of the submerged catalysis/membrane filtration (catalysis/MF) system for phenol hydroxylation over TS-1 based on the material balance of the phenol under steady state and the reported kinetic studies. Based on the developed model, the theoretical phenol conversions at steady state could be calculated using the kinetic parameters obtained from the previous batch experiments. The theoretical conversions are in good agreement with the experimental data obtained in the submerged catalysis/MF system within relative error of +/- 5%. The model can be used to determine the optimal experimental conditions to carry out the phenol hydroxylation over TS-1 in the submerged catalysis/MF system.