Vapor-liquid equilibria of carbon dioxide+n-propanol at elevated pressure

Jun-Hyuk Yim; Youn Geun Jung; Jong Sung Lim

Korean Journal of Chemical Engineering, Vol.27, No.1, 284-288, January, 2010

DOI10.1007/s11814-009-0342-0 Export Citation

Vapor-liquid equilibria of carbon dioxide+n-propanol at elevated pressure

Jun-Hyuk Yim, Youn Geun Jung, and Jong Sung Lim^†

Department of Chemical and Biomolecular Engineering, Sogang University, 1142, Seoul 121-742, Korea

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High-pressure vapor-liquid equilibrium data were measured for the binary mixtures of CO(2)+n-propanol at various isotherms (313.15-343.15 K). The vapor and liquid compositions and pressures were measured in a circulation-type apparatus. To facilitate easy equilibration, both vapor and liquid phases were circulated separately in the experimental apparatus and the equilibrium composition was analyzed by an on-line gas chromatograph. The experimental data were compared with literature results and correlated with the Peng-Robinson (PR) equations of state using the Wong-Sandler mixing rules. Calculated results with PR EOS showed good agreement with our experimental data.

Keywords:High-pressure VLE;Carbon Dioxide;n-Propanol;Peng-Robinson Equation of State;Wong-Sandler Mixing Rule;SCORR

[References]

Fornari RE, Alessi PK, Fluid Phase Equil., 57, 1 (1990)
BORCHJENSEN C, STABY A, MOLLERUP J, J. Supercrit. Fluids, 7(4), 231 (1994)
McHugh MA, Krukonis VJ, Supercritical fluid extraction, Butterworth-Heinemann, Stoneham (1994)
Suzuki K, Sue H, Itou M, Smith RL, Inomata H, Arai K, Saito S, J. Chem. Eng. Data, 35, 63 (1990)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Wong DSH, Sandler SI, AIChE J., 38, 671 (1992)
Seong G, Yoo KP, Lim JS, J. Chem. Eng. Data, 53, 2783 (2008)
Seong GY, Kim AR, Yoo KP, Lim JS, Korean J. Chem. Eng., 26(1), 206 (2009)
Wong DSH, Orbey H, Sandler SI, Ind. Eng. Chem. Res., 31, 2033 (1992)
Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)
McLinden MO, Klein SA, Lemmon EW, Peskin AP, Thermodynamic properties of refrigerants and refrigerant mixtures database (REFPROP), V.6.01, NIST (1998)

[Related Articles]

[1] Fornari RE, Alessi PK, Fluid Phase Equil., 57, 1 (1990)

[2] BORCHJENSEN C, STABY A, MOLLERUP J, J. Supercrit. Fluids, 7(4), 231 (1994)

[3] McHugh MA, Krukonis VJ, Supercritical fluid extraction, Butterworth-Heinemann, Stoneham (1994)

[4] Suzuki K, Sue H, Itou M, Smith RL, Inomata H, Arai K, Saito S, J. Chem. Eng. Data, 35, 63 (1990)

[5] Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)

[6] Wong DSH, Sandler SI, AIChE J., 38, 671 (1992)

[7] Seong G, Yoo KP, Lim JS, J. Chem. Eng. Data, 53, 2783 (2008)

[8] Seong GY, Kim AR, Yoo KP, Lim JS, Korean J. Chem. Eng., 26(1), 206 (2009)

[9] Wong DSH, Orbey H, Sandler SI, Ind. Eng. Chem. Res., 31, 2033 (1992)

[10] Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)

[11] McLinden MO, Klein SA, Lemmon EW, Peskin AP, Thermodynamic properties of refrigerants and refrigerant mixtures database (REFPROP), V.6.01, NIST (1998)