Nano-structured PdxP1-x (x=0-1) composite catalysts supported on Ti substrate are successfully prepared by electrodeposition method, and the morphology and phase of the catalysts are analyzed by field emission scanning electron microscope (FE-SEM) and X-ray energy dispersion spectroscopy (EDS). The activity and stability of the PdxP1-x/Ti composite catalysts are assessed for the electrooxidation of alcohols (methanol, ethanol and 2-propanol) in alkaline medium using cyclic voltammetry and chronoamperometry techniques. The results show that the Pd and Pt form PdxP1-x nano-structured composite catalysts, uniformly distributed on the Ti substrate. The electrocatalytic activity and stability of the PdxP1-x nanocatalysts depend strongly on the atomic ratios of Pd and Pt. Among the synthesized catalysts, the Pd0.8Pt0.2/Ti displays the best catalytic activity and stability for the electrooxidation reaction of alcohols investigated in alkaline medium under conditions in this study, and shows the potential as electrocatalysts for direct alcohol fuel cells. (C) 2009 Elsevier Ltd. All rights reserved.