Fluid Phase Equilibria, Vol.277, No.2, 87-95, 2009
Conductivity, apparent molar volume and isentropic compressibility of 12-tungstosilicic acid and potassium 12-tungstosilicate in aqueous solutions at different temperatures
12-Tungstosilicic acid and potassium 12-tungstosilicate were synthesized and conductivities, densities and ultrasound velocities of their aqueous solutions were studied in the 283.15-303.15 K temperature range at 5 K intervals. Apparent molar volume and apparent molar isentropic compressibility of 12-tungstosilicic acid and potassium 12-tungstosilicate and isentropic compressibility of the studied aqueous solutions have been determined from the experimental density and sound velocity data. (c) 2008 Elsevier B.V. All rights reserved.
Keywords:Polyoxometalate;12-Tungstosilicic acid;Potassium 12-tungstosilicate;Conductivity;Apparent molar volume;Isentropic compressibility