Journal of Applied Electrochemistry, Vol.39, No.10, 1809-1819, 2009
Electrochemical evaluation of aminotriazole corrosion inhibitor under flow conditions
The primary purpose of this study was to investigate the effect that turbulent pipe flow has on the electrochemical behaviour of a 3-amino-1,2,4-triazole (aminotriazole or 3-AT)-based corrosion inhibitor. The experiments were carried out in a 4-L laboratory pipe loop. A metallic ring made of API X52 pipeline steel was located in a linear segment of the pipe loop and acted as a test electrode. The test environment used in all experiments was a 3% NaCl solution saturated with CO2 at 20 A degrees C. The range of Reynolds number studied was from 6518 to 32118, assuring turbulent flow conditions in the pipe loop. Electrochemical impedance spectroscopy (EIS) was used to determine the electrochemical behavior of the steel in the environment at different flow rates and inhibitor concentrations. It was found that the electrochemical impedance of the system is dependent on both exposure time and flow conditions (Reynolds number). It was also detected that EIS data can give information on the persistence of the inhibitor film formed upon the metal surface. Therefore, in order to qualify the performance of the corrosion inhibitor, it is necessary to define the flow conditions at which it is intended to work.