The recycled polystyrene (rPS) was toughened with ethylene-octylene copolymer thermoplastic elastomer (POE) and high-density polyethylene (HDPE) with various melt flow index (MFI), compatibilized by styrene-butadiene-styrene copolymer (SBS) to enhance the toughness of rPS for use as TV backset. The rPS/POE binary blends exhibited an increased impact strength with 5-10 wt % POE content followed by a decrease with the POE content up to 20 wt %, which could be due to poor compatibility between POE and rPS. For rPS/POE/Sl3S ternary blends with 20 wt % of POE content, the impact strength increased dramatically and a sharp brittle-ductile transition was observed as the SBS content was around 3-5 wt %. Rheological study indicated a possible formation of network structure by adding of SBS, which could be a new mechanism for rPS toughening. In rPS/POE/HDPE/SBS (70/20/5/5) quaternary blends, a fibril-like structure was observed as the molecular weight of HDPE was higher (with lower MR). The presence of HDPE fibers in the blends could not enhance the network structure, but could stop the crack propagation during fracture process, resulting in a further increase of the toughness. The prefared quaternary blend showed an impact strength of 9.3 kJ/m(2) and a tensile strength of 25 MPa, which can be well used for TV backset to substitute HIPS because this system is economical and environmental friendly. (c) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 109: 3725-3732,2008