화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.110, No.2, 747-752, 2008
Effects of the filler loading and aging time on the mechanical and electrical conductivity properties of carbon black filled natural rubber
The effects of the filler loading and aging time on the mechanical and electrical conductivity properties of natural rubber were investigated. In this work, carbon black (type N220) was used as a filler, and its loading was varied from 0 to 50 phr. The mechanical properties (e.g., the tensile strength and catastrophic tearing energy) increased with a filler loading up to a certain loading, and a decrease in the mechanical properties was observed with higher filler loadings. The tensile strength and catastrophic tearing energy of the aged samples decreased after 3 and 6 days of aging at 100 degrees C. The results for the electrical conductivity properties of unaged samples showed a percolation threshold at 20 phr, and the values with consistent with further filler loadings. After aging, the percolation threshold was still maintained at 20 phr. The morphologies of unaged and aged samples were significantly different: holes were observed to occur in the age samples. This might have been due to the movement of fillers when the materials were subjected to heat, and this subsequently influenced the mechanical properties of the natural rubber composites. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 110:747-752 2008