Two novel liquid crystalline epoxy resins (LCER) based on bisphenol-S mesogen, 4,4'-Bis-(2,3-epoxypropyloxy)-sulfonyl bis(1,4-phenylene) (p-BEPSBP) and sulfonyl bis(4,1-phenylene) bis[4-(2,3-epoxypropyloxy)benzoate] (p-SBPEPB), were synthesized. Their liquid crystalline behavior and structure were characterized by Fourier transmittance infrared ray (FTIR), differential scanning calorimetry (DSc), (HNMR)-H-1, polarized optical microscopy (POM) and X-ray diffraction (XRD). The results show that p-BEPSBI is a kind of thermotropic liquid crystal and has a smectic mesophase with a melting point (T-m) at 165 degrees C; the p-SBPEPB is a kind of nematic mesophase with the temperature range of 155-302 degrees C from the T-m to the clearing point T-i. The curing behaviors and texture of the liquid crystalline epoxy resins with 4,4'-diaminodiphenyl ether (DDE) were also studied by DSC and some kinetic parameters were evaluated according to the Ozawa's method. The dynamic mechanical properties of curing products were also investigated by torsional braid analysis (TBA), and the results Suggest that the dynamic mechanical loss peak temperature (T-p) of p-BEPSBP/DDE and p-SBPEPB/DDE is 120 and 130 degrees C, respectively. (c) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 110: 3671-3677, 2008