화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.112, No.5, 3103-3109, 2009
Morphology-Related Packetlike Space-Charge Behavior in Linear Low-Density Polyethylene Doped with Al2O3 Nanoparticles
Packetlike space-charge behavior and the isothermal decay processes of the injected charge in neat linear low-density polyethylene (LLDPE) and LLDPE doped with Al2O3 nanoparticles were investigated by the pressure wave propagation method. The I-mm sheet samples, sandwiched by serniconcluctive electrodes, were submitted to 40 kV/nim of direct current field at various temperatures for 3 h. The charge-injecting rate and the apparent mobility of packetlike space charge under direct-current stress were compared among the samples subjected to different blending processes with or without nanoparticles. The slight doping concentration showed a significant influence on the space-charge dynamics, with a lower injecting rate and apparent mobility for higher doped samples. The isothermal decay processes of the injected charge indicated trap-modulated features. The phenomena were considered to be related to the changing morphology of the matrix material. (c) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 112: 3103-3109, 2009