The electrical conduction in solution-grown polymethylmethacrylate (PMMA), polyvinylidenefluoride (PVDF) and PMMA-PVDF double-layered samples in the sandwich configuration (metal-polymer-metal) was investigated at different fields in the range 100-120 kV/cm as a function of temperature in the range 293-423 K for samples of constant thickness of about 50 mu m. Certain effects which lead to a large burst of current immediately after the application of field were observed in double-layered samples. An attempt was made to identify the nature of the current by comparing the observed dependence on electric field, electrode material and temperature with the respective characteristic features of the existing theories on electrical conduction. The observed linear IN characteristics show that the electrical conduction follows Pool-Frenkel mechanism in PMMA and PVDF samples. Whereas, the non-linear behavior of current-voltage measurements in PMMA-PVDF double-layered samples have been interpreted on the basis of space charge limited conduction (SCLC) mechanism. The conductivity of the polymer films increased on formation of their double-layer laminates. The polymer-polymer interface act as charge carrier trapping centres and provides links between the polymer molecules in the amorphous region. The interfacial phenomenon in polymer-polymer heterogeneous system has been interpreted in terms of Maxwell-Wagner model. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 114: 222-230, 2009