Journal of Applied Polymer Science, Vol.114, No.6, 3420-3427, 2009
Synthetic Paper from Plastic Waste: Influence of a Surface Treatment with Corona Discharge
Polymers generally have a chemically inert surface, are nonporous, and have low surface energy, which is characterized by their relatively weak adhesion to other materials. Numerous methods have been developed to modify polymer surfaces chemically. This study was an investigation of how the surface energy of synthetic paper (composite film) could be altered after treatment by corona discharge and of the stability of the surface energy of a film produced from postconsumer polypropylene (PP). A PP/filler (70/30 w/w) composite film was processed in a single-screw extruder with a flat-film dye. In this study, the film stretching rate and electric charge potential of the film surface treatment were the process parameters analyzed. The results showed that the conditions of the surface treatment by corona discharge and the presence of a filler (calcium carbonate) influenced some surface properties: the contact angle, surface energy, and ink adhesion. The surface energy of the composite film increased from 38.7 x 10(-3) N/m(2) without treatment to 52.3 x 10(-3) N/m(2) with treatment. (C) 2009 Wiley Periodicals, Inc. J AppI Polym Sci 114:3420-3427,2009