12 hybrid photocatalysts consisting of titania (TiO2) and an adsorbent such as mordenite were investigated for the photocatalytic decomposition of toluene, a major indoor contaminant in indoor air. The highest decomposition rate was obtained with the use of mordenite and silicon dioxide(SiO2) as additives to TiO2. The photocatalytic activities of hybrid photocatalysts in decomposing toluene are 1.33 times as high as pure P25 at the net weight loading of 0.49 mg/cm(2) under the test condition. Scanning electron microscopy (SEM) images confirmed that the hybrid photocatalyst films were very porously distributed; TiO2 was adsorbed on the surface of mordenite and SiO2, increasing the reaction area of TiO2. The unimolecular Langmuir-Hishelwood model and mass-transfer-based (MTB) method were used to evaluate the reaction coefficients and adsorption equilibrium coefficients of hybrid photocatalysts. It is evidenced that the reaction areas of two, hybrid photocatalysts were 1.52 and 1.64 times larger than that of P25, respectively, which is the major reason to make the high removal efficiency of toluene. (C) 2009 Elsevier B.V. All rights reserved.