Supported hydroxy socialite (H-SOD) membranes were prepared on alpha-alumina disks using direct hydrothermal synthesis at 413 K for 3.5 h. The continuity of the membranes was verified using single gas permeation of He and N-2 at ambient conditions. The membranes were impermeable to N2 and He, which validated absence of defects in the membrane structure. The membranes were used in dewatering several organic alcohol/water mixtures (organic alcohol being: methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 1-pentanol, and 2-pentanol). The influence of feed temperature (303-473 K), feed concentration (0-100 mol% alcohol in the feed), and absolute feed pressure (1.6-2.4 MPa) on the water flux were analyzed. The absolute feed pressure had no effect on the water permeance. The membrane exhibited a water/alcohol separation factor larger than 106 and showed excellent thermal, mechanical, and operation stability in continuously dehydrating a water/ethanol mixture (72 mol% water) by pervaporation at 473 K and 2.2 MPa for 125 h. The normalized water flux correlated well with the water feed concentration for the primary alcohols. Below 40 mol% water in mixtures with secondary alcohols the water flux was three orders of magnitude lower. The water mobility through the membrane had an activation energy of similar to 15 kJ/mol. (C) 2008 Elsevier B.V. All rights reserved.