Porous stainless steel (PSS) supported TiO2 membrane was synthesized from colloidal TiO2 sol by the sol-gel technique. Morphology and phase structure of the obtained membranes were regulated through optimizing the synthesis parameters including organic binders, aging periods of the parent sol and concentrations of the casting solutions as well as the sintering temperatures. Polyvinyl alcohol (PVA) 1750 was found to be feasible to fabricate TiO2 membrane with relatively flat surface and homogeneous morphology without crack. The aging period of the parent sol, which was revealed to be very important to the morphology of the particles deposited in the membranes on PSS, was decided to be 24 h. The concentration, under which the membranes could avoid macro-pores and have a uniform thickness of approximately 8 mu m, was regulated to 0.0036 mol/l. Besides, a homogeneous microstructure with grain sizes of 0.08-0.2 mu m was obtained in the membrane with a pure rutile phase when sintered at 850 degrees C. The obtained PSS supported TiO2 membrane with homogeneous microstructure and rutile phase may be very promising for practical applications. (C) 2008 Elsevier B.V. All rights reserved.