This paper presents an experimental and theoretical study on facilitated transport of lignosulfonate (LS) through a flat sheet supported liquid membrane using trioctylamine (TOA) as carrier and dichloroethane as diluent. The studies were carried out with various support materials and operating conditions (viz. carrier concentration, strip phase concentration, salt concentration, etc.) and their effects on the transport of LS. The results were analyzed to identify a suitable combination of support and operating condition that would yield best performance of the supported liquid membrane (SLM) in terms of fast and efficient transport of LS. The stability of the SLM was assessed in terms of loss of liquid from the pores of membrane support. The SLM is found to be stable till 10 h. Co-transport mechanism has been adopted in this work by using NaOH as the strip phase. It was observed that extraction of LS is increased with increase in concentration of NaOH up to a limiting value of 0.5 M NaOH. Difference of salt concentration between feed and strip phase considerably affect the separation process. The diffusional resistances of organic membrane (Delta org) and aqueous solution (Delta aq) calculated from the permeation model, which is again a combination of three unique mechanisms viz., diffusion through a feed aqueous layer, a fast interfacial chemical reaction, and diffusion of carrier-complex through the organic membrane, are found to be 609.9 and 176.6 s cm(-1), respectively. The values of the diffusion coefficient in the membrane (D,,) and in the bulk organic phase (D-complex) are 1.67 x 10(-9) and 6.68 x 10(-8) m(2)s(-1), respectively. The extraction of LS is about 90%. Nearly 43% of LS can be recovered at optimum condition. (C) 2009 Elsevier B.V. All rights reserved.