화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.21, No.1, 34-39, February, 2010
Export Citation
그라프트 중합에 의해 만들어진 폴리아크릴아마이드-실리카 나노 입자의 특성
The Characteristics of Poly(acrylamide)-SiOx Nanoparticles Prepared by Graft-polymerizaton
민준호, 민성기†
  • 부경대학교 응용화학공학부
Jun Ho Min, and Seong Kee Min†
  • Division of Chemical Engineering, Pukyong National University, Busan 608-739, Korea
E-mail:
초록
γ-Methacryloxypropyl이 가진 기능성 그룹으로 silica nanoparticle의 유기변형은 silica의 표면개질로 성공적으로 준비했다. 또한 ethanol 용매에서 AAm을 사용하는 radical 침전중합을 통해서 polyacrylamide를 MPSN nanosphere에 ‘graft from’ 방법으로 microsphere가 성공적으로 graft중합되었다. FTIR과 XPS는 ultra-fine silica particle의 표면에서 실리카 개질이 공유결합하는 것을 보여주며 SEM분석은 ultra-fine particle과 유기변형된 입자는 각각 25, 30, 35 nm의 크기로 응집작용을 효과적으로 막아주고 나누어줌을 증명할 수 있다는 것을 보여준다
Methacryloxypropyltrimethoxysilane (MPTMS) was used for the surface modification of silica nanoparticles in the toluene dispersion system for 8 h (MPSN). Then, methacryloxypropyl-modified silica nanoparticles were successfully prepared by solutioun polymerization in the ethanol solution at 60 ℃ for 14 h with adding AIBN initiator. The modification of ultra-fine particles (SiOx-PAA nanospheres) was investigated via EA, XPS, FTIR, TGA, SEM and TEM. The mean diameter of the bare silica nanoparticles, MPSN and SiOx-PAA monodisperse nanoparticles was about 25, 30 and 35 nm, respectively.
Keywords:MPSN;MPTMS;nanospheres;monodisperse;graft
  1. Lovell PA, El-Aasser MS, In Emulsion polymerization and Emulsion polymer. Wiley, New York (1997)
  2. Bigelow WC, Pickett DL, Zisman WA, J. Colloid Interface Sci., 1, 513 (1946)
  3. Sagiv J, J. Am. Chem. Soc., 102, 92 (1980)
  4. Nuzzo RG, Allora DL, J. Am. Chem. Soc., 105, 4481 (1983)
  5. Ulman A, Chem. Rev., 96(4), 1533 (1996)
  6. Ni HM, Kawaguchi H, J. Polym. Sci. A: Polym. Chem., 42(11), 2823 (2004)
  7. Ho M, Cai M, Pemberton JE, Anal. Chem., 69, 2613 (1997)
  8. Airoldi C, Monteiro OAC, J. Appl. Polym. Sci., 77(4), 797 (2000)
  9. Das KG, Controlled Release Technology, Bioengineering Aspects, Wiley, New York (1983)
  10. Haga Y, Inoue S, Sato T, Yosomiya R, Angew. Makromol. Chem., 139, 49 (1986)
  11. Mayes G, Mosbach K, Trends Anal. Chem., 16, 321 (1997)
  12. Sellergren B, Dauwe C, Schneider T, Macromolecules, 30(8), 2454 (1997)
  13. Takenaga M, Serizawa Y, Azechi Y, Ochiai A, Kosaka Y, Igarashi R, Mizushima Y, J. Control. Release, 52, 81 (1998)
  14. Gauthier C, Thollet G, Vigier G, Bourgeat-Lami E, Guyot A, Polym. Adv. Technol., 6, 345 (2003)
  15. Laruelle G, Parvole J, Francois J, Billon L, Polymer, 45(15), 5013 (2004)
  16. Sondi I, Fedynyshyn TH, Sinta R, Matijevic E, Langmuir, 16(23), 9031 (2000)
  17. Yang ZZ, Qiu D, Li J, Macromol. Rapid Commun., 23(8), 479 (2002)
  18. Zhang SW, Zhou SX, Weng YM, Wu LM, Langmuir, 21, 2124 (2008)
  19. Erdem B, Sudol ED, Dimonie VL, El-Aasser MS, Macromol. Sym., 155, 81 (2000)
  20. Yu DG, An JH, Colloids Surfaces A: Physicochem. Eng. Aspects, 237, 87 (2004)
  21. Yu DG, An JH, Bae JY, Kim S, Lee YE, Alm SD, Kang SY, Suh KS, Colloids Surfaces A: Physicochem. Eng. Aspects, 245, 29 (2004)
  22. Seul SD, Lee SR, Kim YH, J. Polym. Sci. A: Polym. Chem., 42(16), 4063 (2004)
  23. Yang Y, Kong XZ, Kan CY, Sun CG, Polym. Adv. Technol., 10, 54 (1999)
  24. Quaroni L, Chumanov G, J. Am. Chem. Soc., 121(45), 10642 (1999)
  25. Kim JH, Lee TR, Chem. Mater., 16, 3647 (2004)
  26. Goh ECC, Stover HDH, Macromolecules, 35(27), 9983 (2002)
  27. Gao J, Frisken BJ, Langmuir, 19(13), 5212 (2003)
  28. Gao J, Frisken BJ, Langmuir, 19(13), 5217 (2003)
  29. Gan DJ, Lyon LA, Macromolecules, 35(26), 9634 (2002)
  30. Jones CD, Lyon LA, Macromolecules, 36(6), 1988 (2003)
  31. Downey JS, Frank RS, Li WH, Stover HDH, Macromolecules, 32(9), 2838 (1999)
  32. Li WH, Stover HDH, J. Polym. Sci. A: Polym. Chem., 36(10), 1543 (1998)
  33. Naka Y, Kaetsu I, Yamamoto Y, Hayashi K, J. Polym. Sci. Part A: Polym. Chem., 29, 1197 (1991)
  34. Naka Y, Yamamoto Y, J. Polym. Sci. Part A: Polym. Chem., 30, 2149 (1992)
  35. Pelton RH, Chibante P, Colloids Surf., 20, 247 (1986)
  36. Kawaguchi H, Kawahara M, Yaguchi N, Hoshino F, Ohtsuka Y, Polym. J., 20, 903 (1988)
  37. Kawaguchi H, Yamada Y, Kataoka S, Morita Y, Ohtsuka Y, Polym. J., 23, 955 (1991)
  38. Kamijo Y, Preparation and Characterization of Hydrogel Microspheres, Thesis MS, Keio University, Yokohama, Japan (1995)
  39. Tseng CM, Lu YY, El-Aasser MS, Vanderhoff JW, J. Polym. Sci. Part A: Polym. Chem., 24, 2995 (1986)
  40. Tuncel A, Kahraman R, Piskin E, J. Polym. Sci., 50, 303 (1993)
  41. Chen Y, Yang H, J. Polym. Sci. Part A: Polym. Chem., 30, 2765 (1992)
  42. Kobayashi S, Uyama H, Choi JY, Matsumoto Y, Polym. Int., 30, 265 (1993)
  43. Ni HM, Du YZ, Ma GH, Nagai M, Omi S, Macromolecules, 34(19), 6577 (2001)
  44. Ni HM, Ma GH, Nagai M, Omi S, J. Appl. Polym. Sci., 82(11), 2679 (2001)
  45. Ni HM, Ma GH, Nagai M, Omi S, J. Appl. Polym. Sci., 82(11), 2692 (2001)