Journal of Physical Chemistry A, Vol.113, No.52, 14583-14590, 2009
Photoinduced Processes in Hydrogen Bonded System: Photodissociation of Imidazole Clusters
The photodissociation of imidazole in hydrogen bonded clusters has been studied at photodissociation wavelengths 243 and 193 nm. Imidazole clusters of different mean cluster sizes n approximate to 3 and 6 have been produced in expansions with He and Ar carrier gases, and the mean cluster sizes were determined by mass spectrometric and crossed beam scattering experiments. Simultaneously, the (C3N2H4)(n) clusters were studied by ab initio calculations for n up to 4 molecules, confirming the hydrogen bond N-H center dot center dot center dot N motif in the clusters. The measured H-fragment kinetic energy distribution spectra exhibit a bimodal character similar to the KEDs found for the bare molecule.(1) At 243 run the fast H-atoms originate from the direct dissociation process on the repulsive pi sigma* state, and the slow component results from the dynamics Populating the vibrationally hot ground state via all S-1/S-0 conical intersection. In the clusters the contribution of the slow component increases with the cluster size. The slow component is also dominant at the shorter wavelength of 193 nm, where the dynamics starts with the excitation of pi pi* state. It is shown that the slow component in our experiment is a product of Subsequent two-photon absorption. We have proposed different mechanisms how the observed enhanced internal conversion can be rationalized. The increased stability with respect to the H-fragmet dissociation in clusters call be caused either by hydrogen transfer in the N-H center dot center dot center dot N bond or by closing the pi sigma* dissociation channel as in the ease of pyrrole clusters.