Organic photovoltaic devices promise low-cost, flexible options for future renewable energy that will reduce reliance on oil. Single-wall carbon nanotubes (SWCNTs) provide possibilities for increasing the efficiency of organic solar cells through increasing conductivity of composites used in such devices or through use as a charge acceptor in a bulk heterojunction device. We present data to indicate the physical interaction of SWCNTs with a conjugated polymer, poly[2'-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), oil the basis of the spectroscopic assignments of various conformational species of different optical signature in N,N-dimethylacetamide (DMA) dispersions. We go on to show that energy transfer from nonaggregated MEH-PPV leads to enhanced SWCNT fluorescence in solutions of poorer solvent quality. Energy transfer from polymer chain lengths that are torsionally restricted is not observed. This would Suggest that any electron transfer taking place is occurring through a concerted Dexter mechanism and that use of SWCNTs as an electron acceptor will likely have associated drawbacks.