Two commonly used ionic liquids (ILs), 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) and 1-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6]), as well as binary and ternary mixtures of them with water and/or supercritical CO2 (scCO(2)) were investigated by means of infrared spectroscopy at high pressure. The experiments were performed using attenuated total reflection (ATR) infrared spectroscopy on dry and wet ILs at 40 degrees C and pressures up to 150 bar of scCO(2). The studies indicate that the content of water does not change significantly the solubility of CO2 in the ionic liquids tested. Furthermore, the presence of water does not change significantly the interaction between the IL anion and CO2, which explains why the presence of water in IL does not modify the solubility of CO2 in the system, even in the case of an initial molar ratio of similar to 50/50 of water in [bmim][BF4]. We show that despite the limited solubility of water in supercritical CO2 an ionic liquid can be efficiently dried using sCCO(2) extraction even in the case of a hydrophilic ionic liquid (e.g., [bmim][BF4]). During the scCO(2) extraction, the concentration of water was followed in situ using attenuated total reflection (ATR) infrared spectroscopy. After extraction, no residual water could be detected by this technique, which corresponds approximately to a water concentration of below 320 ppm.