The melting behavior and the crystallization kinetics of random poly(propylene/neopenthyl terephthalate) copolymers (PPT-PNT) were investigated by means of differential scanning calorimetry and hot-stage optical microscopy. Multiple endotherms were evidenced in the PPT-PNT samples, due to melting and recrystallization processes, similarly to PPT. By applying the Hoffman-Weeks' method, the T-m degrees of the copolymers was derived. Baur's equation described well the T-m-composition data. The isothermal crystallization kinetics was analyzed according to the Avrami's treatment. The introduction of NIT units decreased the crystallization rate in comparison to pure PPT. Values of the Avrami's exponent close to three were obtained in all cases, regardless of T-c, in agreement with a crystallization process originating from predeterminated nuclei and characterized by three dimensional spherulitic growth. As a matter of fact, space-filling spherulites were observed by optical microscopy at all TcS. Banded spherulites were found for PPT-PNT5 and PPT-PNT10, the band spacing being affected by both T-c and composition. (C) 2008 Wiley Periodicals, Inc.