Gel polymer electrolyte films comprised of 50% epoxidised natural rubber polymer host, lithium triflate salt (LiCF3SO3), and ethylene carbonate (EC) or propylene carbonate (PC) plasticizer are Prepared using the solution-casting technique. AC impedance studies show that the electrical conductivity of the electrolytes is dependent on both the salt and plasticizer concentrations. The highest room temperature conductivity of 4.92 x 10(-4) S cm(-1) is achieved when 10 wt.% propylene carbonate is introduced into the system containing 1.0 g 50% epoxidised natural rubber polymer doped with 35 wt.% LiCF3SO3. Conductivity studies of these polymer electrolytes are carried out at various temperatures and are found to obey the Vogel-Tamman-Fulcher (VTF) rule. The highest conducting plasticized sample is used as a gelled electrolyte for lithium-air cells. (C) 2008 Elsevier B.V. All rights reserved.