Journal of the American Chemical Society, Vol.130, No.32, 10460-10460, 2008
Cyclic single-molecule magnet in heterospin system
The 2:2 complex of Co-carbene is generated by photolysis of [Co(hfpip)(2) (D2py(2)(TBA))](2), 1, having a cyclic structure functioning as a single-molecule magnet with U-eff = 96 K and H-c = 10 kOe at 1.9 K after annealing at 70 K.