화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.131, No.39, 13886-13886, 2009
Development of New Conjugated Polymers with Donor-pi-Bridge-Acceptor Side Chains for High Performance Solar Cells
Two new conjugated polymers have been designed and synthesized for polymer solar cells. Both of them exhibit excellent photovoltaic properties with a power conversion efficiency as high as 4.74%. Different from the traditional linear donor-acceptor (D-A) type conjugated polymers, these newly designed polymers have a two-dimensional conjugated structure with their tunable acceptors located at the end of D-A side chains and connected with the donors on the main chain through an efficient in-bridge. This approach provides great flexibility in fine-tuning the absorption spectra and energy levels of the resultant polymers for achieving high device performance.