Journal of Industrial and Engineering Chemistry, Vol.16, No.1, 140-146, January, 2010
Removal of ozone from air by absorption in a rotating packed bed
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This work investigated the feasibility of ozone (O3) absorption by H2O2 solution in a rotating packed bed (RPB). The overall volumetric gas-phase mass transfer coefficients (K(G)a) were determined as functions of pH of H2O2 solution, O3 concentration, H2O2 concentration, RPB speed, gas flowrate, liquid flow rate, and RPB type. The K(G)a values were highly dependent on the pH of H2O2 solution. Also, the K(G)a values increased with O3 concentration and H2O2 concentration. As expected, the RPB speed positively affected the K(G)a values for all RPBs. Furthermore, the obtained results indicated that the K(G)a values increased as the inner radius of the bed was increased and the outer radius of the bed was decreased. Moreover, the K(G)a values increased with an increasing liquid flow rate and an increasing gas flow rate for all RPBs. The dependences of K(G)a on the gas flow rate and the liquid flow rate indicated that the resistance to mass transfer in the gas-phase for O3 absorption was higher than that in the liquid phase in the RPB.
- Ramshaw C, Mallinson RH, U.S. Patent 4,283,255 (1981)
- Ramshaw C, Chem. Eng., 389, 13 (1983)
- Kelleher T, Fair JR, Ind. Eng. Chem. Res., 35(12), 4646 (1996)
- Lin CC, Ho TJ, Liu WT, J. Chem. Eng. Jpn., 35(12), 1298 (2002)
- Munjal S, Dudukovic MP, Ramachandran PA, Chem. Eng. Sci., 44, 2245 (1989)
- Kumar MP, Rao DP, Ind. Eng. Chem. Res., 29, 917 (1990)
- Guo F, Zheng C, Guo K, Feng YD, Gardner NC, Chem. Eng. Sci., 52(21-22), 3853 (1997)
- Sandilya P, Rao DP, Sharma A, Biswas G, Ind. Eng. Chem. Res., 40(1), 384 (2001)
- Chen YS, Liu HS, Ind. Eng. Chem. Res., 41(6), 1583 (2002)
- Lin CC, Liu WT, Tan CS, Ind. Eng. Chem. Res., 42(11), 2381 (2003)
- Lin CC, Wei TY, Liu WT, Shen KP, J. Chem. Eng. Jpn., 37(12), 1471 (2004)
- Tan CS, Chen JE, Sep. Purif. Technol., 49(2), 174 (2006)
- Cheng HH, Tan CS, J. Power Sources, 162(2), 1431 (2006)
- Lin CC, Wei TY, Hsu SK, Liu WT, Sep. Purif. Technol., 52(2), 274 (2006)
- Lin CC, Jian GS, Sep. Purif. Technol., 54(1), 51 (2007)
- Lin CC, Chen BC, J. Ind. Eng. Chem., 13(7), 1083 (2007)
- Chen YS, Hsu YC, Lin CC, Tai YD, Liu HS, Environ. Sci. Technol., 42, 2631 (2008)
- Lin CC, Chen BC, J. Ind. Eng. Chem., 14(3), 322 (2008)
- Lin CC, Chen BC, Chen YS, Hsu SK, Sep. Purif. Technol., 62(3), 507 (2008)
- Lin CC, Chien KS, Sep. Purif. Technol., 63(1), 138 (2008)
- Keyvani M, Gardner NC, Chem. Eng. Prog., 85, 48 (1989)
- Singh SP, Wilson JH, Counce RM, Villiers-Fisher JF, Jennings HL, Lucero AJ, Reed GD, Ashworth RA, Elliott MG, Ind. Eng. Chem. Res., 31, 574 (1992)
- Liu HS, Lin CC, Wu SC, Hsu HW, Ind. Eng. Chem. Res., 35(10), 3590 (1996)
- Lin CC, Liu WT, J. Ind. Eng. Chem., 12(3), 455 (2006)
- Peel J, Howarth CR, Ramshaw C, Chem. Eng. Res. Des., 76(5), 585 (1998)
- Chen YS, Lin CC, Liu HS, Ind. Eng. Chem. Res., 44(4), 1043 (2005)
- Chen YS, Lin CC, Liu HS, Ind. Eng. Chem. Res., 44(20), 7868 (2005)
- Chen YS, Lin FY, Lin CC, Tai CYD, Liu HS, Ind. Eng. Chem. Res., 45(20), 6846 (2006)
- Lin CC, Liu WT, J. Ind. Eng. Chem., 13(1), 71 (2007)
- Chen JF, Wang YH, Guo F, Wang XM, Zheng C, Ind. Eng. Chem. Res., 39(4), 948 (2000)
- Lin CC, Liu WT, J. Chem. Technol. Biotechnol., 78(2-3), 138 (2003)
- Chen YH, Chang CY, Su WL, Chen CC, Chiu CY, Yu YH, Chiang PC, Chiang SIM, Ind. Eng. Chem. Res., 43(1), 228 (2004)
- Chen YH, Chang CY, Su WL, Chiu CY, Yu YH, Chiang PC, Chang CF, Shie JL, Chiou CS, Chiang SI, J. Chem. Technol. Biotechnol., 80(1), 68 (2005)
- Chen YH, Chiu CY, Chang CY, Huang YH, Yu YH, Chiang PC, Shie JL, Chiou CS, Ind. Eng. Chem. Res., 44(1), 21 (2005)
- Lin CC, Su YR, Sep. Purif. Technol., 61(3), 311 (2008)
- Staehelin J, Hoigne J, Environ. Sci. Technol., 16, 676 (1982)
- Norman VK, David M, Heather CE, Anal. Chem., 66, 2921 (1994)
- Strigle Jr. RE, Random Packing and Packed Towers: Design and Applications, Gulf Publishing Company, Houston, 1987, p. 61.