Thermodynamic properties such as excess free volume, excess internal pressure, excess isothermal compressibility, and partial molar volumes of binary mixtures of bis(2-methoxyethyl)ether+methyl acetate, + ethyl acetate, + n-butyl acetate, + methyl benzoate, + ethyl benzoate, +methyl salicylate and +diethyl succinate have been studied over the entire mole fraction range at 298.15 K.