화학공학소재연구정보센터
Journal of Vacuum Science & Technology B, Vol.27, No.3, 1620-1624, 2009
Structural anisotropy in a-MgxZn1-xO (0 <= x <= 0.33) films on r-sapphire
The a-plane MgxZn1-xO (0 <= x <= 0.25) films were grown on r-plane (0112) sapphire substrates using metal-organic chemical vapor deposition. Growth was done at temperatures from 520 degrees C, with a typical growth rate of similar to 500 nm/h. Film thickness was varied by changes in deposition time, while Mg/Zn metal-organic flow was varied for changes in Mg composition. The a-plane films are dense and uniform. Strain anisotropy in the films was characterized by synchrotron x-ray diffraction. In-plane strain anisotropy increases with an increase in ZnO film thickness and reduces with an increase in Mg composition of MgxZn1-xO. The surface of the films characterized by atomic force microscopy showed rippled morphology with needles running along the surface. The morphology anisotropy in the films increases with an increase in ZnO film thickness and reduces with Mg composition of MgxZn1-xO films. The morphology anisotropy with ZnO film thickness and Mg composition of MgxZn1-xO is correlated with respective strain anisotropy variation.