Korean Journal of Chemical Engineering, Vol.2, No.1, 55-61, March, 1985
DISPERSION OF SUPPORTED PLATINUM CATALYSTS IN OXYGEN I. EXPERIMENTAL EVIDENCES OF REDISPERSION
The redispersion of platinum on -Al2O3, SiO2 and TiO2 is experimentally studied by means of hydrogen chemisorption, XRD, TEM, and cyclohexene hydrogenation. The increase in dispersion following treatment in oxygen below 600℃ occurs only for Pt/ -Al2O3. For Pt/TiO2, only the presence of chloride during oxidation brings about a significant redispersion. For Pt/SiO2, redispersion does not occur under any condition. Redispersion can occur only in the presence of platinum oxide which can be stabilized by forming a complex with the support. The methods for determining whether or not redispersion will occur for any system and the conditions needed for redispersion are discussed.