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Journal of the Electrochemical Society, Vol.157, No.3, H328-H331, 2010
Nanocomposite Counter Electrode Materials for Electrochromic Windows
Nickel-oxide-based nanocomposite films were deposited using radio-frequency magnetron sputtering from ceramic targets composed of lithium, nickel, and tungsten oxides. The resulting films are partially prelithiated and exhibit a slight spectral shift relative to tungsten-free films when colored. Electron microscopy and X-ray diffraction show that the films are composed of nanocrystallites with NiO structure. The films show promise as electrochromic counter electrode layers that are durable, efficient, and fabricated using a scalable, economical process.
Keywords:electrochemical electrodes;electrochromism;electron microscopy;nanocomposites;nanofabrication;nickel compounds;sputter deposition;thin films;X-ray diffraction