Dispersion polymerization of N-vinyl-2-pyrrolydone using fluorine-based surfactants in supercritical carbon dioxide

Jungin Shin; Won Bae; Hwayong Kim

Korean Journal of Chemical Engineering, Vol.27, No.3, 1021-1027, March, 2010

DOI10.1007/s11814-010-0137-3 Export Citation

Dispersion polymerization of N-vinyl-2-pyrrolydone using fluorine-based surfactants in supercritical carbon dioxide

Jungin Shin, Won Bae¹, and Hwayong Kim^†

School of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University, 559 Gwanangno, Gwanak-gu, Seoul 151-744, Korea
¹R&D Institute, Miwon Specialty Chemical Co., Ltd., 405-3, Moknae-dong, Ansan-si, Gyeonggi 425-100, Korea

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We carried out a dispersion polymerization of N-vinyl-2-pyrrolydone using fluorine-based surfactants, which included poly(heptadecafluorodecyl acrylate) (PHDFDA) or poly(heptadecafluorodecyl methacrylate) (PHDFDMA) in supercritical carbon dioxide (scCO2). An FE-SEM and an image analyzer were used to characterize particle morphology, size, and size distribution of the resulting polymer taking into account effect of the surfactant, initiator, and monomer concentrations.

Keywords:N-vinyl-2-pyrrolydone;Supercritical Carbon Dioxide;Dispersion Polymerization

[References]

DeSimone JM, Tumas W, Green chemistry using liquid and supercritical carbon dioxide, Oxford University Press, Inc. (2003)
McHugh MA, Krukonis VJ, Supercritical fluid extraction: principle and practice, 2nd Ed. Butterworth-Heinemann, Boston. (1994)
Cooper AI, J. Mater. Chem., 10, 207 (2000)
Beckman EJ, J. Supercrit. Fluids, 28(2-3), 121 (2004)
Kendall JL, Canelas DA, Young JL, DeSimone JM, Chem. Rev., 99(2), 543 (1999)
Canelas DA, Betts DE, DeSimone JM, Macromolecules., 28, 2818 (1996)
Shiho H, DeSimone JM, J. Polym. Sci. A: Polym. Chem., 37(14), 2429 (1999)
Tseng CM, Lu YY, El-Aasser MS, Vanderhoff JW, J.Polym. Sci., Part A: Polym. Chem. Ed., 24, 2995 (1986)
Kawaguchi S, Ito KJ, Adv. Poym. Sci., 175, 299 (2005)
Saenx JM, Asua JM, J. Polym. Sci., Part A: Polym. Chem., 33, 1511 (2000)
Carson T, Lizotte J, Desimone JM, Macromolecules, 33(6), 1917 (2000)
Galia A, Giaconia A, Iaia V, Filardo G, J. Polym. Sci. A: Polym. Chem., 42(1), 173 (2004)
Berger T, McGhee B, Scherf U, Steffen W, Macromolecules, 33(10), 3505 (2000)
Kwon S, Lee K, Bae W, Kim H, J. Supercrit. Fluids, 45(3), 391 (2008)
Shin S, Bae W, Lee YW, Kim H, Korean J. Chem. Eng., 24(4), 664 (2007)
Shin J, Oh KS, Bae W, Lee YW, Kim H, Ind. Eng. Chem. Res., 47(15), 5680 (2008)
Saenx JM, Asua JM, J. Polym. Sci., Part A: Polym. Chem., 33, 1511 (2000)
Shin J, Bae W, Lee YW, Kim H, J. Chem. Eng. Data., 51, 1571 (2006)
Shin J, Bae W, Kim H, Lee YW, J. Chem. Eng. Data., 53, 1523 (2008)
Bae W, Kwon SY, Byun HS, Kim HY, J. Supercrit. Fluids, 30(2), 127 (2004)
Hsiao YL, Maury EE, Desimone JM, Mawson S, Johnston KP, Macromolecules, 28(24), 8159 (1995)
Carson T, Lizotte J, Desimone JM, Macromolecules, 33(6), 1917 (2000)

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[1] DeSimone JM, Tumas W, Green chemistry using liquid and supercritical carbon dioxide, Oxford University Press, Inc. (2003)

[2] McHugh MA, Krukonis VJ, Supercritical fluid extraction: principle and practice, 2nd Ed. Butterworth-Heinemann, Boston. (1994)

[3] Cooper AI, J. Mater. Chem., 10, 207 (2000)

[4] Beckman EJ, J. Supercrit. Fluids, 28(2-3), 121 (2004)

[5] Kendall JL, Canelas DA, Young JL, DeSimone JM, Chem. Rev., 99(2), 543 (1999)

[6] Canelas DA, Betts DE, DeSimone JM, Macromolecules., 28, 2818 (1996)

[7] Shiho H, DeSimone JM, J. Polym. Sci. A: Polym. Chem., 37(14), 2429 (1999)

[8] Tseng CM, Lu YY, El-Aasser MS, Vanderhoff JW, J.Polym. Sci., Part A: Polym. Chem. Ed., 24, 2995 (1986)

[9] Kawaguchi S, Ito KJ, Adv. Poym. Sci., 175, 299 (2005)

[10] Saenx JM, Asua JM, J. Polym. Sci., Part A: Polym. Chem., 33, 1511 (2000)

[11] Carson T, Lizotte J, Desimone JM, Macromolecules, 33(6), 1917 (2000)

[12] Galia A, Giaconia A, Iaia V, Filardo G, J. Polym. Sci. A: Polym. Chem., 42(1), 173 (2004)

[13] Berger T, McGhee B, Scherf U, Steffen W, Macromolecules, 33(10), 3505 (2000)

[14] Kwon S, Lee K, Bae W, Kim H, J. Supercrit. Fluids, 45(3), 391 (2008)

[15] Shin S, Bae W, Lee YW, Kim H, Korean J. Chem. Eng., 24(4), 664 (2007)

[16] Shin J, Oh KS, Bae W, Lee YW, Kim H, Ind. Eng. Chem. Res., 47(15), 5680 (2008)

[17] Saenx JM, Asua JM, J. Polym. Sci., Part A: Polym. Chem., 33, 1511 (2000)

[18] Shin J, Bae W, Lee YW, Kim H, J. Chem. Eng. Data., 51, 1571 (2006)

[19] Shin J, Bae W, Kim H, Lee YW, J. Chem. Eng. Data., 53, 1523 (2008)

[20] Bae W, Kwon SY, Byun HS, Kim HY, J. Supercrit. Fluids, 30(2), 127 (2004)

[21] Hsiao YL, Maury EE, Desimone JM, Mawson S, Johnston KP, Macromolecules, 28(24), 8159 (1995)

[22] Carson T, Lizotte J, Desimone JM, Macromolecules, 33(6), 1917 (2000)