The bulk polymerisation of N-vinylcarbazole (NVC) at an elevated temperature in the presence of both multi- and single-walled carbon nanotubes (CNTs) leads to the formation of two different types of composite materials, the morphology and properties of which were characterised by a field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis, and electrical property measurements. The efficiency of CNTs to initiate the NVC polymerisation was investigated using both multi-walled CNTs (MWCNTs) and single-walled CNTs (SWCNTs). The focus was on three major aspects: the degree of polymerisation, the morphology and the properties of the resulting nanocomposite materials. Results showed that SWCNTs were more efficient in initiating NVC polymerisation than MWCNTs, and the morphology of resultant nanocomposites revealed wrapping and grafting of some poly(N-vinylcarbazole) (PNVC) chains on the SWCNT surfaces. The morphology of the PNVC/MWCNT nanocomposites showed only homogeneous wrapping of the outer Surfaces of MWCNTs by PNVC chains. The direct current (dc) electrical conductivity of pure PNVC improved dramatically in the presence of both MWCNTs and SWCNTs, however, the extent of improvement is higher in the case of PNVC/MWCNT nanocomposites. (C) 2008 Elsevier Ltd. All rights reserved.